Pool Chemistry Pilot

Overview

Pool chemistry advice on the internet is an octopus of conflicts of interest: pool-store free water tests that always find something to sell, forum elders who worship one system and damn all others, and apps with subscriptions. Meanwhile the actual chemistry is well understood: chlorine disinfects, CYA buffers it, pH controls everything, and 90% of "my pool is green" is a FC/CYA ratio problem, not a product problem.

This skill is a dosing calculator and diagnostician that works from your test numbers:

1. Dosage engine — exact amounts (g of dichlor, mL of acid, weight of borax…) to move each parameter from measured to target, using your pool's real volume.
2. FC/CYA relationship model — the core physics the pool store won't explain: active chlorine falls as CYA rises; below a threshold, algae outcompete chlorine at full slam levels.
3. Trouble lights — high CYA (the "chlorine lock" myth decoded), CH crashing plaster vs vinyl, salt-cell FC production vs demand, metals staining vs algae. Every recommendation is chemistry-first: dilution or generic chemicals, never branded products (sodium hypochlorite = liquid chlorine = bleach, same molecule).
4. Treatment sequencing — the order matters (pH first when out of range, then chlorine, then clarifiers). Wrong order wastes chemicals; the pilot prints the order.

State is a plain JSON log; the skill never phones home.

When to Use

• "My test reads FC 1, pH 7.8, CYA 90 — what do I add?"
• "Pool went green after rain — do I shock it?"
• "How much acid to go from pH 8.0 to 7.4 in 30,000 L?" (dosing math)
• "Eyes burn after swimming — is it chlorine?" (usually pH, and the skill shows why)
• Planning startup chemistry for a new/refill pool or spring opening
• Deciding drain-vs-no-drain for high CYA (dilution math)
• Saltwater pool: cell output vs demand, when to boost manually

Don't use for: commercial/public pool code compliance (health-department regulations differ; this is residential guidance), pool building/plumbing/hydraulics, or swallowing-the-chemicals emergencies → poison control (US 1-800-222-1222) / emergency services.

How It Works — Numbered Workflow

1. Set up the pool once: volume in liters or gallons (the script computes volume from pool shape/dimensions if unknown — the #1 dosing error is wrong volume), surface type (plaster/vinyl/fiberglass), and sanitizer type (trichlor/dichlor, liquid/salt).
2. Log test results whenever you test: FC, CC, pH, TA, CH, CYA, salt, borates, temp.
3. Run status — parameter-by-parameter verdict with trouble lights and the FC/CYA ratio check.
4. Run plan — the dosing sequence: what to add, how much, in what order, with 30–60 min re-test circulation pauses between steps.
5. Run slam when fighting algae (see Slam Protocol in references) — it computes the slam FC level from CYA and tracks it daily.
6. Run history to see trends; persistent drift tells you if your TA is too low to hold pH or your fill water is alkali.

Target Ranges (residential, Trouble-Free-Pool-informed)

The FC/CYA rule: maintain FC ≥ 7.5% of CYA (min 3 ppm). At CYA 40 → FC 3 minimum. At CYA 90 → FC 7 minimum and your chlorine is still weaker than tap-water chlorine. High CYA doesn't "lock" chlorine; it hides it in reserve — but the active fraction is what kills algae, and it's tiny. That's the physics pool stores monetize.

Quick Start

python3 scripts/pool_pilot.py setup --liters 45000 --surface plaster --sanitizer swg
#   (or --gallons 12000; or --shape rect --length 9 --width 4.5 --avg-depth 1.3 --unit metric)

python3 scripts/pool_pilot.py log --fc 1.5 --cc 0.5 --ph 7.8 --ta 90 --ch 350 --cya 80 --temp 27
python3 scripts/pool_pilot.py status
python3 scripts/pool_pilot.py plan --ph-target 7.4            # full dosing sequence
python3 scripts/pool_pilot.py slam                            # algae kill protocol
python3 scripts/pool_pilot.py history                         # trend table

State: pool_state.json beside the script. Pure stdlib. No network.

Chemistry cheat-sheet (what each chemical does)

Full table, TA/CH/CYA interactions, and the slam-level table: references/pool-chemistry.md.

Common Pitfalls

1. Wrong pool volume. Every dose scales with volume; a 20% volume error is a 20% dosing error. setup --shape computes it from dimensions; when in doubt, do the salt-rise method (add known kg salt, measure ppm rise).
2. Chasing pH with product instead of aeration. pH constantly rises in outdoor pools from CO2 outgassing; the fix is lower TA, not endless acid-and-backwashing.
3. Ignoring CC. Combined chlorine is "used up" chlorine holding organics; persistent CC > 0.5 means under-chlorination or ammonia in the water. That's a slam, not a shock-and-hope.
4. Trichlor in a hot tub / small vinyl pool. Trichlor is acidic (pH ~3) and adds CYA relentlessly; in small volumes CYA rockets. Dichlor same problem, gentler. For spas: liquid chlorine or lithium hypochlorite, or bromine. CYA runaway is the #1 "why is my pool always green" root cause.
5. Shocking by "1 lb per 10k gal" folklore. Shock level is a function of CYA: CYA 30 → slam 12; CYA 70 → slam 28. One-size shocks under-dose at high CYA (looks like "chlorine demand" and sells more product).
6. Adding chemicals simultaneously or in the wrong order. pH must be in range before you judge chlorine efficacy; acid and chlorine 30 min apart, pump running. The plan command sequences automatically.
7. Testing at the wrong time. FC falls through the day (sun consumes CYA-buffered chlorine); test at the same hour daily or your trend is noise.
8. Pool-store CYA tests over-reporting. The turbidimetric CYA test reads high at high CYA (dilution error compounding); if the melamine test says >90, dilute the sample 1:1 with distilled water, re-test, double the reading.

Verification Checklist

• setup wrote pool_state.json with volume/surface/sanitizer
• log of a full test panel then status prints a verdict per parameter + FC/CYA ratio
• plan prints grams/mL per chemical with a sequence and re-test pauses
• slam computes slam FC from CYA and prints the daily checklist
• history shows the logged trend
• No network imports (grep requests/urllib/socket — empty)

One-Shot Recipes

"Green pool after a storm":

python3 scripts/pool_pilot.py log --fc 0 --cc 1.0 --ph 7.2 --cya 45
python3 scripts/pool_pilot.py slam     # → slam level 18 ppm, brush 2x/day, filter 24/7, re-test FC nightly, keep FC at slam until FC holds overnight + water clear

"Eyes burn — too much chlorine?"

python3 scripts/pool_pilot.py log --fc 3 --ph 8.2 --ta 130 --cya 40
python3 scripts/pool_pilot.py plan    # → pH 8.2 is the culprit; acid dose to 7.4, then aeration, then drop TA

"CYA is 90 — drain?"

python3 scripts/pool_pilot.py log --cya 90
python3 scripts/pool_pilot.py plan --cya-target 40   # → 55% dilution or drain to 40% and refill (dilution math printed)

Safety

Chemicals are hazardous. Always add acid to water (never water to acid), wear eye protection, never mix chlorine with acid (chlorine gas), store locked away from children. Pool chemistry is safe when respected. If swallowed: US Poison Control 1-800-222-1222, EU 112.

License & Disclaimer

MIT. Residential guidance from standard pool chemistry; not a substitute for public-pool regulatory compliance or professional service. Generic chemical names only — no brand affiliations.